Specific heat of combustion of concrete. Heat of combustion. Initial data for calculating the specific temporary fire load in premises

Chemical reactions are accompanied by the absorption or release of energy, in particular heat. reactions accompanied by the absorption of heat, as well as the compounds formed during this process, are called endothermic . In endothermic reactions, heating of the reacting substances is necessary not only for the occurrence of the reaction, but also during the entire time of their occurrence. Without external heating, the endothermic reaction stops.

reactions accompanied by the release of heat, as well as the compounds formed during this process, are called exothermic . All combustion reactions are exothermic. Due to the release of heat, they, having arisen at one point, are able to spread to the entire mass of reacting substances.

The amount of heat released during complete combustion of a substance and related to one mole, unit of mass (kg, g) or volume (m 3) of a combustible substance is called heat of combustion. The heat of combustion can be calculated from tabular data using Hess's law. Russian chemist G.G. Hess in 1840 discovered a law that is a special case of the law of conservation of energy. Hess's law is as follows: the thermal effect of a chemical transformation does not depend on the path along which the reaction occurs, but depends only on the initial and final states of the system, provided that the temperature and pressure (or volume) at the beginning and end of the reaction are the same.

Let's consider this using the example of calculating the heat of combustion of methane. Methane can be produced from 1 mole of carbon and 2 moles of hydrogen. When methane is burned, it produces 2 moles of water and 1 mole of carbon dioxide.

C + 2H 2 = CH 4 + 74.8 kJ (Q 1).

CH 4 + 2O 2 = CO 2 + 2H 2 O + Q horizon.

The same products are formed by the combustion of hydrogen and carbon. During these reactions, the total amount of heat released is 963.5 kJ.

2H 2 + O 2 = 2H 2 O + 570.6 kJ

C + O 2 = CO 2 + 392.9 kJ.

Since the initial and final products are the same in both cases, their total thermal effects must be equal according to Hess's law, i.e.

Q 1 + Q mountains = Q,

Q mountains = Q - Q 1. (1.11)

Therefore, the heat of combustion of methane will be equal to

Q mountains = 963.5 - 74.8 = 888.7 kJ/mol.

Thus, the heat of combustion of a chemical compound (or their mixture) is equal to the difference between the sum of the heats of formation of combustion products and the heat of formation of the burned chemical compound (or substances that make up the combustible mixture). Therefore, to determine the heat of combustion of chemical compounds, it is necessary to know the heat of their formation and the heat of formation of the products obtained after combustion.

Below are the heats of formation of some chemical compounds:

Aluminum oxide Al 2 O 3 ………		Methane CH 4 …………………………
Iron oxide Fe 2 O 3 …………		Ethane C 2 H 6 ……………………
Carbon monoxide CO………….		Acetylene C 2 H 2 ………………
Carbon dioxide CO2………		Benzene C 6 H 6 …………………
Water H 2 O ………………………….		Ethylene C 2 H 4 …………………
Water vapor H 2 O ……………		Toluene C 6 H 5 CH 3 …………….

Example 1.5 .Determine the combustion temperature of ethane if the heat of its formationQ 1 = 88.4 kJ. Let's write the combustion equation for ethane.

C 2 H 6 + 3.5O 2 = 2 CO 2 + 3 H 2 O + Qmountains.

For determiningQmountainsit is necessary to know the heat of formation of combustion products. the heat of formation of carbon dioxide is 396.9 kJ, and that of water is 286.6 kJ. Hence,Qwill be equal

Q = 2 × 396,9 + 3 × 286.6 = 1653.6 kJ,

and the heat of combustion of ethane

Qmountains= Q - Q 1 = 1653.6 - 88.4 = 1565.2 kJ.

The heat of combustion is experimentally determined in a bomb calorimeter and a gas calorimeter. There are higher and lower calorific values. Higher calorific value Q in is the amount of heat released during the complete combustion of 1 kg or 1 m 3 of a combustible substance, provided that the hydrogen contained in it burns to form liquid water. Lower calorific value Qn is the amount of heat released during the complete combustion of 1 kg or 1 m 3 of a combustible substance, provided that hydrogen is burned until water vapor is formed and the moisture of the combustible substance is evaporated.

The higher and lower heats of combustion of solid and liquid combustible substances can be determined using the formulas of D.I. Mendeleev:

where Q in, Q n - higher and lower calorific values, kJ/kg; W – content of carbon, hydrogen, oxygen, combustible sulfur and moisture in the combustible substance, %.

Example 1.6. Define lowest temperature combustion of sulfur fuel oil, consisting of 82.5% C, 10.65% H, 3.1%Sand 0.5% O; A (ash) = 0.25%,W = 3%. Using the equation of D.I. Mendeleev (1.13), we obtain

=38622.7 kJ/kg

The lower calorific value of 1 m3 of dry gases can be determined by the equation

Lower heat combustion of some flammable gases and liquids, obtained experimentally, is given below:

Hydrocarbons: methane………………………..
ethane …………………………
propane………………………
methyl………………….
ethyl……………………
propyl………………………

The lower calorific value of some combustible materials, calculated from their elemental composition, has the following values:

Gasoline……………………		Synthetic rubber
Paper ……………………		Kerosene………………
Wood		Organic glass..
air-dry………..		Rubber ………………..
in building structures...		Peat ( W = 20 %) …….

There is a lower limit of calorific value, below which substances become incapable of combustion in the air atmosphere.

Experiments show that substances are non-flammable if they are not explosive and if their lower calorific value in air does not exceed 2100 kJ/kg. Consequently, the heat of combustion can serve as an approximate estimate of the flammability of substances. However, it should be noted that the flammability of solids and materials largely depends on their condition. Thus, a sheet of paper, easily ignited by the flame of a match, when applied to the smooth surface of a metal plate or concrete wall, becomes difficult to combust. Consequently, the flammability of substances also depends on the rate of heat removal from the combustion zone.

In practice, during the combustion process, especially in fires, the heat of combustion indicated in the tables is not completely released, since combustion is accompanied by underburning. It is known that petroleum products, as well as benzene, toluene, acetylene, i.e. substances rich

carbon, burn in fires with the formation of a significant amount of soot. Soot (carbon) can burn and produce heat. If it is formed during combustion, then, consequently, the combustible substance emits less heat than the amount indicated in the tables. For substances rich in carbon, the underburning coefficient h is 0.8 - 0.9. Consequently, in fires when burning 1 kg of rubber, not 33520 kJ can be released, but only 33520´0.8 = 26816 kJ.

Fire size is usually characterized by the area of ​​the fire. The amount of heat released per unit area of ​​fire per unit time is called heat of fire Q p

QP= Qnυ mh ,

Where υ m– mass burnout rate, kg/(m 2 ×s).

The specific heat of fire during internal fires characterizes the thermal load on the structures of buildings and structures and is used to calculate the fire temperature.

1.6. Combustion temperature

The heat released in the combustion zone is perceived by the combustion products, so they heat up to a high temperature. The temperature to which combustion products are heated during combustion is called combustion temperature . There are calorimetric, theoretical and actual combustion temperatures. The actual combustion temperature for fire conditions is called fire temperature.

The calorimetric combustion temperature is understood as the temperature to which the products of complete combustion are heated under the following conditions:

1) all the heat released during combustion is spent on heating the combustion products (heat loss is zero);

2) the initial temperatures of air and flammable substances are 0 0 C;

3) the amount of air is equal to the theoretically required (a = 1);

4) complete combustion occurs.

The calorimetric combustion temperature depends only on the composition of the combustible substance and does not depend on its quantity.

Theoretical temperature, in contrast to calorimetric temperature, characterizes combustion taking into account the endothermic process of dissociation of combustion products at high temperature

2СО 2 2СО + О 2 - 566.5 kJ.

2H 2 O2H 2 + O 2 - 478.5 kJ.

In practice, the dissociation of combustion products must be taken into account only at temperatures above 1700 0 C. During diffusion combustion of substances in fire conditions, the actual combustion temperatures do not reach such values, therefore, to assess fire conditions, only the calorimetric combustion temperature and the fire temperature are used. There is a distinction between internal and external fire temperatures. The internal fire temperature is the average temperature of the smoke in the room where the fire occurs. External fire temperature – flame temperature.

When calculating the calorimetric combustion temperature and the internal fire temperature, it is assumed that the lower heat of combustion Qn of a combustible substance is equal to the energy qg required to heat the combustion products from 0 0 C to the calorimetric combustion temperature

, - heat capacity of the components of combustion products (heat capacity of CO 2 is taken for a mixture of CO 2 and SO 2), kJ/(m 3 ? K).

In fact, not all the heat released during combustion under fire conditions is spent on heating the combustion products. Most of it is spent on heating structures, preparing flammable substances for combustion, heating excess air, etc. Therefore, the temperature of an internal fire is significantly lower than the calorimetric temperature. The combustion temperature calculation method assumes that the entire volume of combustion products is heated to the same temperature. In reality, the temperature at different points of the combustion center is not the same. The highest temperature is in the region of space where the combustion reaction occurs, i.e. in the combustion (flame) zone. The temperature is significantly lower in places where there are flammable vapors and gases released from the burning substance and combustion products mixed with excess air.

In order to judge the nature of temperature changes during a fire depending on various combustion conditions, the concept of average volumetric fire temperature was introduced, which is understood as the average value of the temperatures measured by thermometers at various points of the internal fire. This temperature is determined from experience.

What is fuel?

This is one component or a mixture of substances that are capable of chemical transformations associated with the release of heat. Different types fuels differ in their quantitative content of oxidizer, which is used to release thermal energy.

In a broad sense, fuel is an energy carrier, that is, a potential type of potential energy.

Classification

Currently, fuel types are divided according to their state of aggregation into liquid, solid, and gaseous.

Natural hard materials include stone, firewood and anthracite. Briquettes, coke, thermoanthracite are types of artificial solid fuel.

Liquids include substances containing substances of organic origin. Their main components are: oxygen, carbon, nitrogen, hydrogen, sulfur. Artificial liquid fuel will be a variety of resins and fuel oil.

Gaseous fuel is a mixture of various gases: ethylene, methane, propane, butane. In addition to them, the composition contains carbon dioxide and carbon monoxide, hydrogen sulfide, nitrogen, water vapor, oxygen.

Fuel indicators

The main indicator of combustion. The formula for determining the calorific value is considered in thermochemistry. emit “standard fuel”, which implies the calorific value of 1 kilogram of anthracite.

Household heating oil is intended for combustion in heating devices of low power, which are located in residential premises, heat generators used in agriculture for drying feed, canning.

The specific heat of combustion of a fuel is a value that demonstrates the amount of heat that is generated during the complete combustion of fuel with a volume of 1 m 3 or a mass of one kilogram.

To measure this value, J/kg, J/m3, calorie/m3 are used. To determine the heat of combustion, the calorimetry method is used.

With an increase in the specific heat of combustion of fuel, the specific fuel consumption decreases, and the efficiency remains unchanged.

The heat of combustion of substances is the amount of energy released during the oxidation of a solid, liquid, or gaseous substance.

It is determined by the chemical composition, as well as the state of aggregation of the combustible substance.

Features of combustion products

The higher and lower calorific values ​​are related to the state of aggregation of water in the substances obtained after combustion of fuel.

The higher calorific value is the amount of heat released during complete combustion of a substance. This value also includes the heat of condensation of water vapor.

The lowest working heat of combustion is the value that corresponds to the release of heat during combustion without taking into account the heat of condensation of water vapor.

The latent heat of condensation is the amount of energy of condensation of water vapor.

Mathematical relationship

The higher and lower calorific values ​​are related by the following relationship:

QB = QH + k(W + 9H)

where W is the amount by weight (in %) of water in a flammable substance;

H is the amount of hydrogen (% by mass) in the combustible substance;

k - coefficient equal to 6 kcal/kg

Methods for performing calculations

The higher and lower calorific values ​​are determined by two main methods: calculation and experimental.

Calorimeters are used to carry out experimental calculations. First, a sample of fuel is burned in it. The heat that will be released is completely absorbed by the water. Having an idea of ​​the mass of water, you can determine by the change in its temperature the value of its heat of combustion.

This technique is considered simple and effective; it only requires knowledge of technical analysis data.

In the calculation method, the higher and lower calorific values ​​are calculated using the Mendeleev formula.

Q p H = 339C p +1030H p -109(O p -S p) - 25 W p (kJ/kg)

It takes into account the content of carbon, oxygen, hydrogen, water vapor, sulfur in the working composition (in percent). The amount of heat during combustion is determined taking into account the equivalent fuel.

The heat of combustion of gas allows preliminary calculations to be made and the effectiveness of using a certain type of fuel to be determined.

Features of origin

In order to understand how much heat is released when a certain fuel is burned, it is necessary to have an idea of ​​its origin.

In nature, there are different versions of solid fuels, which differ in composition and properties.

Its formation occurs through several stages. First peat is formed, then it becomes brown and coal, then anthracite is formed. The main sources of solid fuel formation are leaves, wood, and pine needles. When parts of plants die and are exposed to air, they are destroyed by fungi and form peat. Its accumulation turns into a brown mass, then brown gas is obtained.

At high blood pressure and temperature, brown gas turns into coal, then the fuel accumulates in the form of anthracite.

In addition to organic matter, the fuel contains additional ballast. Organic is considered to be that part that is formed from organic substances: hydrogen, carbon, nitrogen, oxygen. In addition to these chemical elements, it contains ballast: moisture, ash.

Combustion technology involves the separation of the working, dry, and combustible mass of burned fuel. The working mass is the fuel in its original form supplied to the consumer. Dry mass is a composition in which there is no water.

Compound

The most valuable components are carbon and hydrogen.

These elements are contained in any type of fuel. In peat and wood, the percentage of carbon reaches 58 percent, in hard and brown coal - 80%, and in anthracite it reaches 95 percent by weight. Depending on this indicator, the amount of heat released during fuel combustion changes. Hydrogen is the second most important element of any fuel. When it binds with oxygen, it forms moisture, which significantly reduces the thermal value of any fuel.

Its percentage ranges from 3.8 in oil shale to 11 in fuel oil. The oxygen contained in the fuel acts as ballast.

It is not a heat-generating chemical element, therefore it negatively affects the value of its heat of combustion. The combustion of nitrogen, contained in free or bound form in combustion products, is considered harmful impurities, therefore its quantity is clearly limited.

Sulfur is included in fuel in the form of sulfates, sulfides, and also as sulfur dioxide gases. When hydrated, sulfur oxides form sulfuric acid, which destroys boiler equipment and negatively affects vegetation and living organisms.

That is why sulfur is a chemical element whose presence in natural fuel is extremely undesirable. If sulfur compounds get inside the work area, they cause significant poisoning of operating personnel.

There are three types of ash depending on its origin:

• primary;
• secondary;
• tertiary

The primary species is formed from minerals found in plants. Secondary ash is formed as a result of plant residues entering sand and soil during formation.

Tertiary ash appears in the composition of fuel during extraction, storage, and transportation. With significant ash deposition, a decrease in heat transfer on the heating surface of the boiler unit occurs, reducing the amount of heat transfer to water from gases. A huge amount of ash negatively affects the operation of the boiler.

Finally

Volatile substances have a significant influence on the combustion process of any type of fuel. The greater their output, the larger the volume of the flame front will be. For example, coal and peat ignite easily, the process is accompanied by minor heat losses. The coke that remains after removing volatile impurities contains only mineral and carbon compounds. Depending on the characteristics of the fuel, the amount of heat changes significantly.

Depending on the chemical composition There are three stages of solid fuel formation: peat, brown coal, and coal.

Natural wood is used in small boiler installations. They mainly use wood chips, sawdust, slabs, bark, and the firewood itself is used in small quantities. Depending on the type of wood, the amount of heat generated varies significantly.

As the heat of combustion decreases, firewood acquires certain advantages: rapid flammability, minimal ash content, and the absence of traces of sulfur.

Reliable information about the composition of natural or synthetic fuel, its calorific value, is an excellent way to carry out thermochemical calculations.

Currently, there is a real opportunity to identify those main options for solid, gaseous, liquid fuels that will be the most effective and inexpensive to use in a certain situation.

Combustible material		Combustible material	Heat of combustion, MJ× kg -1
Paper loosened	13,4	Phenoplastics	11,3
Staple fiber	13,8	Cotton loosened	15,7
Wood in products	16,6	Amyl alcohol	39,0
Carbolite products	24,9	Acetone	20,0
Synthetic rubber	40,2	Benzene	40,9
Organic glass	25,1	Petrol	41,9
Polystyrene	39,0	Butyl alcohol	36,2
Polypropylene	45,6	Diesel fuel	43,0
Polyethylene	47,1	Kerosene	43,5
Rubber products	33,5	Fuel oil	39,8
Oil	41,9	Ethanol	27,2

The specific fire load q, MJ× m -2 is determined from the relationship, where S is the area where the fire load is located, m 2 (but not less than 10 m 2).

Task Determine the fire hazard category of the premises with an area of ​​S=84 m2.

The room contains: 12 tables made of wood chip material weighing 16 kg each; 4 stands made of wood chip material weighing 10 kg each; 12 benches made of chipboard, 12 kg each; 3 cotton curtains, 5 kg each; fiberglass board weighing 25 kg; linoleum weighing 70 kg.

Solution

1. The lower calorific value of the materials in the room is determined (Table 7.6):

Q =16.6 MJ/kg – for tables, benches and stands;

Q =15.7 MJ/kg – for curtains;

Q =33.5 MJ/kg – for linoleum;

Q =25.1 MJ/kg – for a fiberglass board.

2. Using formula 7.9, the total fire load in the room is determined

3. Specific fire load q is determined

Comparing the obtained values ​​of q = 112.5 with the data given in Table 7.4, we assign the premises to category B4 in terms of fire hazard.

RADIATION SAFETY

8.1. Basic concepts and definitions

Question What kind of radiation is called ionizing radiation?

Answer Ionizing radiation (hereinafter referred to as IR) is radiation whose interaction with a substance leads to the formation of ions of different signs in this substance. AI consists of charged (a and b particles, protons, fragments of fission nuclei) and uncharged particles (neutrons, neutrinos, photons).

Question What physical quantities characterize the interaction of AI with matter and with biological objects?

Answer The interaction of an AI with a substance is characterized by the absorbed dose.

Absorbed dose D is the main dosimetric quantity. It is equal to the ratio of the average energy dw transferred by ionizing radiation to a substance in an elementary volume to the mass dm of the substance in this volume:

The energy can be averaged over any given volume, in which case the average dose will be equal to the total energy delivered to the volume divided by the mass of that volume. In the SI system, the absorbed dose is measured in J/kg and has a special name gray (Gy). Non-systemic unit – rad, 1rad = 0.01 Gy. The dose increment per unit time is called dose rate:

To assess the radiation hazard of chronic human exposure, according to [8.2], special physical quantities are introduced - equivalent dose in an organ or tissue H T, R and effective dose E.

Equivalent dose H T,R – absorbed dose in an organ or tissue T, multiplied by the corresponding weighting factor for a given type of radiation W R:

Н T,R =W R × D T,R , (8.3)

where D T,R is the average absorbed dose in tissue or organ T;

W R – weighting factor for type R radiation.

When exposed various types AI with different weighting factors W R equivalent dose is defined as the sum of equivalent doses for these types of AI:

(8.4)

The values ​​of the weighting coefficients are given in table. 8.1 [8.1] .

The calorific value is understood as the heat of complete combustion of a unit mass of a substance. It takes into account heat losses associated with the dissociation of combustion products and the incompleteness of chemical combustion reactions. Calorific value is the maximum possible heat of combustion per unit mass of a substance.

Determine the calorific value of elements, their compounds and fuel mixtures. For elements, it is numerically equal to the heat of formation of the combustion product. The calorific value of mixtures is an additive quantity and can be found if the calorific value of the components of the mixture is known.

Combustion occurs not only due to the formation of oxides, therefore, in a broad sense, we can talk about the calorific value of elements and their compounds not only in oxygen, but also when interacting with fluorine, chlorine, nitrogen, boron, carbon, silicon, sulfur and phosphorus.

Calorific value is important characteristic. It allows you to evaluate and compare with others the maximum possible heat release of a particular redox reaction and determine in relation to it the completeness of the actual combustion processes. Knowledge of the calorific value is necessary when selecting fuel components and mixtures for various purposes and when assessing their completeness of combustion.

There are higher H in and below H n calorific value. Higher calorific value, in contrast to lower calorific value, includes the heat of phase transformations (condensation, solidification) of combustion products when cooled to room temperature. Thus, the highest calorific value is the heat of complete combustion of a substance when the physical state of the combustion products is considered at room temperature, and the lowest calorific value is at the combustion temperature. The higher calorific value is determined by burning the substance in a calorimetric bomb or by calculation. It includes, in particular, the heat released during the condensation of water vapor, which at 298 K is equal to 44 kJ/mol. The lower calorific value is calculated without taking into account the heat of condensation of water vapor, for example, using the formula

Where % H is the percentage of hydrogen in the fuel.

If calorific value values ​​indicate the physical state of the combustion products (solid, liquid or gaseous), then the “highest” and “lowest” subscripts are usually omitted.

Let us consider the calorific value of hydrocarbons and elements in oxygen per unit mass of the original fuel. The lower calorific value differs from the highest for paraffins by an average of 3220-3350 kJ/kg, for olefins and naphthenes - by 3140-3220 kJ/kg, for benzene - by 1590 kJ/kg. When experimentally determining the calorific value, it should be borne in mind that in a calorimetric bomb the substance burns at a constant volume, and in real conditions, often at a constant pressure. The correction for the difference in combustion conditions ranges from 2.1 to 12.6 for solid fuel, about 33.5 for fuel oil, 46.1 kJ/kg for gasoline, and reaches 210 kJ/m3 for gas. In practice, this correction is introduced only when determining the calorific value of the gas.

For paraffins, the calorific value decreases with increasing boiling point and increasing C/H ratio. For monocyclic alicyclic hydrocarbons this change is much less. In the benzene series, the calorific value increases when moving to higher homologues due to the side chain. Dinuclear aromatic hydrocarbons have a lower calorific value than the benzene series.

Only a few elements and their compounds have a calorific value that exceeds the calorific value of hydrocarbon fuels. These elements include hydrogen, boron, beryllium, lithium, their compounds and several organoelement compounds of boron and beryllium. The calorific value of elements such as sulfur, sodium, niobium, zirconium, calcium, vanadium, titanium, phosphorus, magnesium, silicon and aluminum lies in the range of 9210-32,240 kJ/kg. For the remaining elements of the periodic system, the calorific value does not exceed 8374 kJ/kg. Data on the gross calorific value of various classes of fuels are given in table. 1.18.

Table 1.18

Gross calorific value of various combustibles in oxygen (per unit mass of fuel)

Substance
Carbon monoxide
iso-butane
n-Dodecane
n-Hexadecane
Acetylene
Cyclopentane
Cyclohexane
Ethylbenzene
Beryllium
Aluminum
Zirconium
Beryllium hydride
Psntaboran
Metadiborane
Ethyldiborane

For liquid hydrocarbons, methanol and ethanol, heating values ​​are based on the liquid starting state.

The calorific value of some fuels was calculated on a computer. It is 24.75 kJ/kg for magnesium and 31.08 kJ/kg for aluminum (the state of the oxides is solid) and practically coincides with the data in Table. 1.18. The highest calorific value of paraffin C26H54, naphthalene C10H8, anthracene C14H10 and methenamine C6H12N4 are 47.00, 40.20, 39.80 and 29.80, respectively, and the lowest calorific value is 43.70, 39.00, 38.40 and 28.00 kJ/kg.

As an example, in relation to rocket fuels, we present the heats of combustion of various elements in oxygen and fluorine, referred to a unit mass of combustion products. The heats of combustion are calculated for the state of combustion products at a temperature of 2700 K and are shown in Fig. 1.25 and in table. 1.19.

Puc. 1.25. Heat of combustion of elements in oxygen (1) and fluorine(2), calculated per kilogram of combustion products

As follows from the data presented, to obtain maximum combustion heat, the most preferred substances are those containing hydrogen, lithium and beryllium, and secondarily, boron, magnesium, aluminum and silicon. The advantage of hydrogen due to the low molecular weight of combustion products is obvious. It should be noted that beryllium has an advantage due to its high heat of combustion.

There is the possibility of the formation of mixed combustion products, in particular gaseous oxyfluorides of elements. Since the oxyfluorides of trivalent elements are usually stable, most oxyfluorides are not effective combustion products rocket fuels due to high molecular weight. The heat of combustion with the formation of COF2 (g) has an intermediate value between the heats of combustion of CO2 (g) and CF4 (g). The heat of combustion with the formation of SO2F2 (g) is greater than in the case of the formation of SO2 (g) or SF6; (G.). However, most rocket fuels contain highly reducing elements that prevent the formation of such substances.

The formation of aluminum oxyfluoride AlOF (g) releases less heat than the formation of oxide or fluoride, so it is not of interest. Boron oxyfluoride BOF (g) and its trimer (BOF)3 (g) are quite important components of the combustion products of rocket fuels. The heat of combustion to form BOF (g) is intermediate between the heats of combustion to form oxide and fluoride, but oxyfluoride is thermally more stable than either of these compounds.

Table 1.19

Heat of combustion of elements (in MJ/kg), per unit mass of combustion products ( T = 2700 K)

			oxyfluoride
Beryllium
Oxygen
Aluminum
Zirconium

When beryllium and boron nitrides are formed, enough a large number of heat, which makes it possible to classify them as important components of rocket fuel combustion products.

In table Table 1.20 shows the highest calorific value of elements when they interact with various reagents, referred to a unit mass of combustion products. The calorific value of elements when interacting with chlorine, nitrogen (except for the formation of Be3N2 and BN), boron, carbon, silicon, sulfur and phosphorus is significantly less than the calorific value of elements when interacting with oxygen and fluorine. The wide variety of requirements for combustion processes and reagents (in terms of temperature, composition, state of combustion products, etc.) makes it advisable to use the data in Table. 1.20 in the practical development of fuel mixtures for one purpose or another.

Table 1.20

Higher calorific value of elements (in MJ/kg) when interacting with oxygen, fluorine, chlorine, nitrogen, per unit mass of combustion products

• See also: Joulin S., Clavin R. Op. cit.

I understand that polymers are a great variety of materials. I was confused by the dimension 18 kJ/kg, namely kiloJ/kg (taken from “Fire and explosion hazard of substances and materials and means of extinguishing them” Handbook ed. 2 edited by A.Ya. Korolchenko and D.A. Korolchenko, part I, p. 306, second from the top, if you don’t believe me, I can send it). That's actually why I was indignant.

All the fuss is due to the fact that on the doors of the warehouse, jam-packed with fuel, there is a big letter “D”. Well, when the internal audit saw it, it started cackling and flapping its wings (completely justified). I was burned - here is a guy who can count categories. Chief: "Count." OK. I came, tried them on, figured out the range of materials, looked at the ceiling, and there the amount of stored fuel was all indicated (well, sometimes you’re lucky), I did the math. They gave it to her - she (as I understand it, a former RTN inspector) said: how can you confirm the amount of stored materials. I told her: “What’s the difference in the world? The room is small - an AUPT is still not required. There is nothing explosive, and according to “B” the coolest is accepted. The fire barriers are all in place and satisfy even SP, even SNiP. And, most importantly, a warehouse consumables, full today, empty tomorrow.” Well, she nodded her head, and then: “Where do you get the exact data on storage in kg?” I decided to change my mind. A fire inspector... Heh. I take a certificate from the warehouse manager: wood - 80 kg, rubber - 140 kg, felt 60 kg, cardboard 310 kg, etc. plus printing. I bring it to her: here is confirmation, try to refute it - the manager knows better what he has stored. She: “Oh! This is another matter - this is a document.” I'm crazy! Well, then I remembered about cartridges. And on Friday she needs to hand over this damn calculation and replace the letter on the gate. We have been spoiling paper for a week now, and at the same time, please note, we work in the same organization. That is, I am distracted from my direct responsibilities, we are doing some nonsense, getting paid, etc. for the sake of one letter on the gate. In short, everything is arranged very efficiently.

But this was a lyrical digression. My goal is to satisfy the auditor (a complete fraud). No one doubts that category B1, but she wants to see cartridges in the calculation. We both don’t know what they are made of. For every unconfirmed value of combustion heat, she snorts like a cat. Snaala didn’t even want to accept the railway VNTP as a certificate - like it doesn’t apply to us. Well, at least the arguments about universal submission to the laws of the universe in general and physics in particular had an effect. Therefore, I choose materials that are available reference books or ND. Manufacturers claim (at least one, but as I talked to them - it’s a joke) that the toner contains graphite. I found it at Korolchenko’s, but it was written crookedly. Thank you, they told me the dimensions on the designers’ forum. I calmed down with this. Now I'm working on plastic. The cartridge body seems to be PVC, but for the same Korolchenko all PVC is white powder. It doesn't look like a cartridge at all. I found vinyl plastic, which is the result of various influences on PVC. HOORAY!!! But there is 18 KILOJ/kg - well, it doesn’t fit into any gates. If it had been written there in human terms - MJ, then yesterday I would have calmed down.